From my .ssh/config
:
Host myshortname realname.example.com
HostName realname.example.com
IdentityFile ~/.ssh/realname_rsa # private key for realname
User remoteusername
Host myother realname2.example.org
HostName realname2.example.org
IdentityFile ~/.ssh/realname2_rsa # different private key for realname2
User remoteusername